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61.
Chengyong Yang Bolong Huang Shuxing Bai Yonggang Feng Qi Shao Xiaoqing Huang 《Advanced materials (Deerfield Beach, Fla.)》2020,32(24):2001267
Electrocatalytic nitrogen reduction reaction (NRR) is a promising process relative to energy-intensive Haber–Bosch process. While conventional electrocatalysts underperform with sluggish paths, achieving dissociation of N2 brings the key challenge for enhancing NRR. This study proposes an effective surface chalcogenation strategy to improve the NRR performance of pristine metal nanocrystals (NCs). Surprisingly, the NH3 yield and Faraday efficiency (FE) (175.6 ± 23.6 mg h–1 g–1Rh and 13.3 ± 0.4%) of Rh-Se NCs is significantly enhanced by 16 and 15 times, respectively. Detailed investigations show that the superior activity and high FE are attributed to the effect of surface chalcogenation, which not only can decrease the apparent activation energy, but also inhibit the occurrence of the hydrogen evolution reaction (HER) process. Theoretical calculations reveal that the strong interface strain effect within core@shell system induces a critical redox inversion, resulting in a rather low valence state of Rh and Se surface sites. Such strong correlation indicates an efficient electron-transfer minimizing NRR barrier. Significantly, the surface chalcogenation strategy is general, which can extend to create other NRR metal electrocatalysts with enhanced performance. This strategy open a new avenue for future NH3 production for breakthrough in the bottleneck of NRR. 相似文献
62.
伴随着我国综合实力的不断提升,信息技术获得了突飞猛进的发展,如今,医疗改革如火如荼地进行,医院的信息管理工作同以往相比较也实现了极大的发展。病案统计工作是指相关工作人员对医院中患者的信息进行全面统计,若是这项工作完成得足够出色,会给医院后续的信息查询工作带来诸多方便和快捷,也能够在某种程度上使医院管理效率和质量实现一定幅度的提升。因此,将信息技术和医院的病案工管理工作进行密切结合,就成为病案管理人员应当重点思考的问题。病案统计工作是医院管理工作中的一个重点环节,病案统计结果能够为医院整体绩效带来十分深远的影响。因此,投入更多时间和精力来提高对这项工作的重视,显得十分关键和重要。文章对信息技术在医院病案统计中的应用展开了分析。 相似文献
63.
64.
Preoperative chemoradiation therapy (CRT) is becoming the standard treatment for patients with locally
advanced rectal cancer. However, individual differences in response to treatment range from a complete response to
complete resistance. Predicting the tumor response to radiotherapy may improve the efficacy of radiotherapy. This
review mainly summarizes recent studies about the molecular biomarkers that can predict the response to
radiotherapy in rectal cancer. These studies have indicated that the molecular markers involved in the response to
radiotherapy mainly include genes related to radiosensitivity, cancer stem cell-related markers, non-coding RNAs
(ncRNAs), single-nucleotide polymorphisms (SNPs) and gene methylation, and other factors including
carcinoembryonic antigen (CEA) level, anemia, lymphocytes, and signaling pathways. Many of these identified
markers are mainly associated with DNA repair, apoptosis, and cell cycle, but some involve unknown cell
mechanisms. We speculate that predictors of radiotherapy response may involve combinations of multiple molecular
biomarkers that may be useful for the development of individualized therapy for rectal cancer patients. 相似文献
65.
针对管道布局、最大允许能耗给定条件下快速热循环注塑成形(RHCM)注塑模具型腔表面快速均匀加热的问题,提出以单根加热棒热流密度为设计变量,以模具型腔表面升温效率和温度分布均匀性为目标,结合有限元模拟、响应面设计以及多目标粒子群优化技术来优化RHCM模具电加热系统。与优化前相比,加热系统优化后,模具型腔表面最大温差降低63.4%,加热系统总能耗降低9%。对比了不同注塑成形工艺条件下成形的平板塑件表面质量,结果表明,相对传统注塑成形(CIM)工艺,RHCM工艺将制品表面粗糙度Ra从320 nm降低到118 nm,并有效抑制了制品表面熔接痕、缩痕等缺陷;发现制品表面粗糙度与型腔表面对应点温度成负相关,说明优化后的型腔表面温度分布更有利于提升制品表面质量。 相似文献
66.
Thermal management and catalytic combustion stability characteristics of premixed methane/air in heat recirculation meso‐combustors 下载免费PDF全文
Yunfei Yan Shuai Feng Zizhen Huang Li Zhang Wenli Pan Lixian Li Zhongqing Yang 《国际能源研究杂志》2018,42(3):999-1012
In order to illuminate heat recirculation effect on catalytic combustion stability and further improve energy conversion efficiency in meso‐combustor, the catalytic combustion characteristics of the combustor with/without preheating channels are numerically studied at steady conditions. It is found that methane conversion rate and combustion efficiency increases by 2% to 3% and approximately 9% in the heat recirculation meso‐combustor, indicating that heat recirculation effect facilitates more complete combustion of methane and medium components. Preheating channels show positive effects on improving combustion stability in the heat recirculation meso‐combustor. On one hand, preheating channels facilitate heat recirculation effect, and heat recirculation rate exceeds 10% for all cases and reaches 31.8% with an inlet velocity of 0.5 m/s, leading to significant increment of methane‐specific enthalpy at the preheating channel outlet. On the other hand, Rh(s)/O(s) ratios of catalytic surface and catalytic surface temperature in main reaction zone are enlarged by the preheating channels, facilitating methane adsorption at catalytic surface. Specially, most of fuels are consumed in a shorter distance with higher methane conversion speed, which brings benefits to promote combustion efficiency and may be helpful to inhibit the combustion instability in heat recirculation meso‐combustors. 相似文献
67.
68.
高熵氧化物作为近几年发展起来的新型氧化物体系,打破了传统掺杂氧化物的设计理念,由五种及以上氧化物以等摩尔或近等摩尔构成,因其具有简单的结构和优异的性能等受到国内外研究人员的广泛关注。高熵氧化物由于多主元且主元之间混乱排列,易形成岩盐型、氟化钙型、尖晶石型或钙钛矿等固溶体结构,从而表现出优异的性能,尤其在能源存储材料和磁性材料方面有十分广阔的应用前景,但目前对高熵氧化物应用研究较少。本工作介绍了国内外高熵氧化物的制备方法,主要包括固相法、热解法、共沉淀法、水热合成法和液相燃烧合成法等,比较了各方法的优缺点和发展前景;归纳了高熵氧化物作为锂离子电极材料、巨介电材料、磁性材料和催化材料等方面的应用;指出了高熵氧化物目前研究存在的问题,讨论了解决措施,展望了高熵氧化物未来的发展趋势。 相似文献
69.
采用等离子堆焊技术在H13钢基体表面上制备了Ni60A/Cr3C2堆焊覆层,研究了覆层的磨损行为和热疲劳性能。在600 ℃下销盘试验的结果表明,镍基碳化铬复合覆层的耐磨性是Ni60A堆焊覆层的2.8倍和基材H13钢的11.6倍。镍基覆层可以显著降低H13钢的摩擦因数,加入碳化铬则会削弱覆层的摩擦性能。随着磨损的进行,主要磨损机理从氧化磨损演变为磨粒磨损和粘着磨损。在800 ℃到室温下的热疲劳测试结果表明,镍基碳化铬复合覆层在48个热循环后疲劳裂纹达到200 μm,早于镍基覆层的62次。这说明高温氧化促进热疲劳裂纹的产生。碳化铬增强相从镍基上剥离,导致镍基复合覆层热疲劳性能下降。 相似文献
70.
Dr. Feng Wang. Dr. Shan Li Taiping Gan Dr. Gordon M. Stott Dr. Andrew Flint Dr. Tsui-Fen Chou 《ChemMedChem》2020,15(8):685-694
Abstract : A major challenge of targeted cancer therapy is the selection for drug-resistant mutations in tumor cells leading to loss of treatment effectiveness. p97/VCP is central regulator of protein homeostasis and a promising anticancer target because of its vital role in cell growth and survival. One ATP-competitive p97 inhibitor, CB-5083, has entered clinical trials. Selective pressure on HCT116 cells dosed with CB-5083 identified five different resistant mutants. Identification of p97 inhibitors with different mechanisms of action would offer the potential to overcome this class of resistance mutations. Our results demonstrate that two CB-5083 resistant p97 mutants, N660 K and T688 A, were also resistant to several other ATP-competitive p97 inhibitors, whereas inhibition by two allosteric p97 inhibitors NMS-873 and UPCDC-30245 were unaffected by these mutations. We also established a CB-5083 resistant cell line that harbors a new p97 double mutation (D649 A/T688 A). While CB-5083, NMS-873, and UPCDC-30245 all effectively inhibited proliferation of the parental HCT116 cell line, NMS-873 and UPCDC-30245 were 30-fold more potent in inhibiting the CB-5083 resistant D649 A/T688 A double mutant than CB-5083. Our results suggest that allosteric p97 inhibitors are promising alternatives when resistance to ATP-competitive p97 inhibitors arises during anticancer treatment. 相似文献